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15240672380's Question
Chemistry
Posted 10 months ago

calculate the pH\mathrm{pH} of a solution that is 0.050M0.050 \mathrm{M} in formic acid and 0.10M0.10 \mathrm{M} in sodium formate
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Answer from Sia
Posted 10 months ago
Solution
1
Use the Henderson-Hasselbalch equation: To find the pH of the buffer solution, we apply the Henderson-Hasselbalch equation, which is given by pH=pKa+log([A][HA])\text{pH} = \text{pKa} + \log\left(\frac{[\text{A}^-]}{[\text{HA}]}\right), where pKa\text{pKa} is the acid dissociation constant of the weak acid, [A][\text{A}^-] is the concentration of the conjugate base, and [HA][\text{HA}] is the concentration of the weak acid
2
Calculate the pH: The pKa of formic acid is approximately 3.75. Using the concentrations given, [A]=0.10 M[\text{A}^-] = 0.10\ \text{M} and [HA]=0.050 M[\text{HA}] = 0.050\ \text{M}. Plugging these values into the Henderson-Hasselbalch equation gives pH=3.75+log(0.100.050)=3.75+log(2)=3.75+0.3010=4.0510\text{pH} = 3.75 + \log\left(\frac{0.10}{0.050}\right) = 3.75 + \log(2) = 3.75 + 0.3010 = 4.0510
Answer
The pH of the solution is 4.0510
Key Concept
Henderson-Hasselbalch equation
Explanation
The Henderson-Hasselbalch equation is used to calculate the pH of a buffer solution based on the concentrations of the acid and its conjugate base.

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