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Chemistry
Posted 8 months ago

c) A 5.0mM5.0 \mathrm{mM} solution of CdC d (II) ion give the diffusion current of 40μA40 \mu \mathrm{A} at constant temperature. Find the diffusion coefficient of CdC d (II) ion. [Given : Rate of flow of mercury =3.2mgs1=3.2 \mathrm{mg} \cdot s^{-1}, Drop time
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Answer from Sia
Posted 8 months ago
Solution
1
Identify the given data: The concentration of Cd2+Cd^{2+} ion is 5.0mM5.0 \, \text{mM}, the diffusion current is 40μA40 \, \mu \text{A}, the rate of flow of mercury is 3.2mgs13.2 \, \text{mg} \cdot \text{s}^{-1}, and the drop time is not provided
2
Use Ilkovic equation: The Ilkovic equation relates the diffusion current (idi_d) to the diffusion coefficient (DD), concentration (CC), and other constants. The equation is id=knFAD1/3Ci_d = k n F A D^{1/3} C, where kk is a constant, nn is the number of electrons, FF is the Faraday constant, AA is the area, and DD is the diffusion coefficient
3
Simplify the equation: Since the drop time and other constants are not provided, we can simplify the equation to id=kD1/3Ci_d = k' D^{1/3} C, where kk' is a combined constant
4
Solve for $D$: Rearrange the equation to solve for DD: D=(idkC)3D = \left( \frac{i_d}{k' C} \right)^3
5
Substitute the values: Substitute id=40μAi_d = 40 \, \mu \text{A} and C=5.0mMC = 5.0 \, \text{mM} into the equation. Note that kk' is not provided, so we cannot calculate the exact value of DD without additional information
Answer
The diffusion coefficient DD cannot be determined exactly without the value of the constant kk'.
Key Concept
Ilkovic equation for diffusion current
Explanation
The Ilkovic equation relates the diffusion current to the diffusion coefficient, concentration, and other constants. Without the value of the combined constant kk', the exact diffusion coefficient cannot be calculated.


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Solution
1
Identify the given data: The student is asking about the best electrical conductor among different solutions
2
Compare conductivity: Electrical conductivity depends on the concentration of ions and their mobility in the solution
3
Determine the best conductor: Generally, solutions with higher ionic concentration and ions with higher mobility will have better conductivity
Answer
The best electrical conductor among different solutions is the one with the highest ionic concentration and ions with the highest mobility.
Key Concept
Electrical conductivity of solutions
Explanation
Electrical conductivity is influenced by the concentration of ions and their mobility in the solution. Higher ionic concentration and higher mobility result in better conductivity.


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Solution
1
Identify the given data: The student is asking about the maximum number of a compound to undergo electrophilic aromatic substitution reaction
2
Determine the compound: Compounds with multiple positions available for substitution, such as benzene rings with multiple substituents, can undergo multiple electrophilic aromatic substitution reactions
3
Identify the positions: The number of available positions for substitution depends on the structure of the compound and the nature of existing substituents
Answer
The maximum number of a compound to undergo electrophilic aromatic substitution reaction depends on the number of available positions on the aromatic ring.
Key Concept
Electrophilic aromatic substitution
Explanation
Electrophilic aromatic substitution reactions occur at positions on the aromatic ring that are available and not sterically hindered by existing substituents.


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Solution
1
Identify the given data: The student is asking about the preparation of a 2.8M2.8 \, \text{M} solution from Methanol and Sodium Carbonate
2
Calculate the moles of solute: To prepare a 2.8M2.8 \, \text{M} solution, calculate the moles of Sodium Carbonate needed for the desired volume of solution
3
Determine the volume of solvent: Calculate the volume of Methanol required to dissolve the calculated moles of Sodium Carbonate to achieve the desired molarity
4
Mix the solution: Dissolve the calculated moles of Sodium Carbonate in the calculated volume of Methanol to prepare the 2.8M2.8 \, \text{M} solution
Answer
To prepare a 2.8M2.8 \, \text{M} solution, calculate the moles of Sodium Carbonate needed and dissolve it in the appropriate volume of Methanol.
Key Concept
Solution preparation
Explanation
Preparing a solution of a specific molarity involves calculating the moles of solute needed and dissolving it in the appropriate volume of solvent.

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