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青州's Question
Chemistry
Posted 10 months ago

(a) At room temperature, H2O\mathrm{H}_{2} \mathrm{O} is a liquid and KNO3\mathrm{KNO}_{3} is a solid. The student incorrectly claims that this is because potassium and nitrate ions experience stronger dispersion forces than H2O\mathrm{H}_{2} \mathrm{O} molecules. In terms of the types of aftractive forces, explain why the student is incorrect.
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Answer from Sia
Posted 10 months ago
Solution
1
Identify the types of intermolecular forces in $\mathrm{H_2O}$ and $\mathrm{KNO_3}$: H2O\mathrm{H_2O} molecules are polar and can form hydrogen bonds, which are a type of strong dipole-dipole interaction. KNO3\mathrm{KNO_3} is an ionic compound, consisting of potassium ions (K+\mathrm{K^+}) and nitrate ions (NO3\mathrm{NO_3^-}), which experience ionic bonding
2
Explain the incorrect claim: Dispersion forces, also known as London dispersion forces, are the weakest type of intermolecular force and are present in all molecules. However, they are not the primary force in either H2O\mathrm{H_2O} or KNO3\mathrm{KNO_3}. The student's claim is incorrect because the primary intermolecular force in H2O\mathrm{H_2O} is hydrogen bonding, not dispersion forces, and the primary force in KNO3\mathrm{KNO_3} is ionic bonding, which is much stronger than dispersion forces
3
Clarify the states of matter: The state of matter (solid, liquid, or gas) at room temperature is determined by the strength of the intermolecular forces. The strong hydrogen bonds in H2O\mathrm{H_2O} allow it to be a liquid at room temperature, while the even stronger ionic bonds in KNO3\mathrm{KNO_3} result in it being a solid
Answer
The student's claim is incorrect because H2O\mathrm{H_2O} molecules are held together by hydrogen bonds, not dispersion forces, and KNO3\mathrm{KNO_3} is held together by ionic bonds, which are stronger than both dispersion forces and hydrogen bonds. This explains why H2O\mathrm{H_2O} is a liquid and KNO3\mathrm{KNO_3} is a solid at room temperature.
Key Concept
Intermolecular forces determine the state of matter
Explanation
H2O\mathrm{H_2O} is a liquid at room temperature due to hydrogen bonding, while KNO3\mathrm{KNO_3} is a solid due to ionic bonding. Dispersion forces are present in both but are not the determining factor for their states of matter.

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