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青州's Question
Chemistry
Posted 9 months ago

Question: The Hf of CO2( g)\mathrm{CO} 2(\mathrm{~g}) is 393.5 kJ/mol-393.5 \mathrm{~kJ} / \mathrm{mol}. The enthalpy of combustion of methane is 890.4 kJ/mole890.4 \mathrm{~kJ} / \mathrm{mole}. Calculate the enthalpy of formation of methane.

The Hf of CO2( g)\mathrm{CO} 2(\mathrm{~g}) is 393.5 kJ/mol-393.5 \mathrm{~kJ} / \mathrm{mol}. The enthalpy of combustion of methane is 890.4 kJ890.4 \mathrm{~kJ} /mole. Calculate the enthalpy of formation of methane.
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Answer from Sia
Posted 9 months ago
Solution
1
Identify the given data: The enthalpy of formation of CO2(g)CO_2(g) is 393.5kJ/mol-393.5 \, \text{kJ/mol} and the enthalpy of combustion of methane is 890.4kJ/mol-890.4 \, \text{kJ/mol}
2
Write the balanced chemical equation for the combustion of methane: CH4(g)+2O2(g)CO2(g)+2H2O(l) CH_4(g) + 2O_2(g) \rightarrow CO_2(g) + 2H_2O(l)
3
Use the enthalpy of formation values: The enthalpy change for the reaction can be calculated using the enthalpies of formation of the products and reactants. The enthalpy of formation of H2O(l)H_2O(l) is 285.8kJ/mol-285.8 \, \text{kJ/mol}
4
Apply Hess's Law: ΔHcombustion=ΔHf(CO2)+2ΔHf(H2O)ΔHf(CH4) \Delta H_{\text{combustion}} = \Delta H_f (CO_2) + 2 \Delta H_f (H_2O) - \Delta H_f (CH_4) Substitute the known values: 890.4kJ/mol=(393.5kJ/mol)+2(285.8kJ/mol)ΔHf(CH4) -890.4 \, \text{kJ/mol} = (-393.5 \, \text{kJ/mol}) + 2(-285.8 \, \text{kJ/mol}) - \Delta H_f (CH_4)
5
Solve for the enthalpy of formation of methane: 890.4=393.5571.6ΔHf(CH4) -890.4 = -393.5 - 571.6 - \Delta H_f (CH_4) 890.4=965.1ΔHf(CH4) -890.4 = -965.1 - \Delta H_f (CH_4) ΔHf(CH4)=965.1+890.4 \Delta H_f (CH_4) = -965.1 + 890.4 ΔHf(CH4)=74.7kJ/mol \Delta H_f (CH_4) = -74.7 \, \text{kJ/mol}
Answer
The enthalpy of formation of methane is 74.7kJ/mol-74.7 \, \text{kJ/mol}.
Key Concept
Enthalpy of formation is the change in enthalpy when one mole of a compound is formed from its elements in their standard states.
Explanation
By using Hess's Law and the given enthalpy values, we can determine the enthalpy of formation of methane by rearranging and solving the equation for the enthalpy of formation.

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