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Sia

青州's Question
Chemistry
Posted 10 months ago

Question 7: Mechanism II ( 6 Marks): In the space provided below please give the detailed mechanism for the following transformation. Please be certain to use good curved arrow notation for your mechanism
Please indicate if you predict this reaction to be exothermic or endothermic in Box A
Mechanism:(5 marks)
Box A: (1 mark)
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Answer from Sia
Posted 10 months ago
Solution
1
Identify the functional groups and reactants: The reactant molecule contains a carbonyl group (C=O) and a double bond within a six-membered ring. The presence of an OH group and a water molecule with a partial positive charge (δ+) suggests a reaction involving these species
2
Propose a mechanism: The mechanism likely involves a nucleophilic attack by the water molecule on the carbonyl carbon, followed by proton transfers to form the product with an OH group replacing the carbonyl group and the addition of two hydrogen atoms to the double bond, resulting in a single bond
3
Predict the reaction enthalpy: The reaction appears to be exothermic because the formation of new bonds in the product releases more energy than is required to break the original bonds in the reactants
Answer
The reaction mechanism involves nucleophilic attack by water, followed by proton transfers, and is predicted to be exothermic.
Key Concept
Reaction Mechanism and Enthalpy Prediction
Explanation
The detailed mechanism involves the addition of water across the carbonyl group and double bond, with subsequent proton transfers leading to the final product. The reaction is exothermic due to the net release of energy from bond formation.

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