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15240672380's Question
Chemistry
Posted 10 months ago

Draw the organic product of the following reaction.
H3CCH2CCCH2CH3
\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{3}

Li/NH3\mathrm{Li} / \mathrm{NH}_{3}
- You do not have to consider stereochemistry.
- You do not have to explicitly draw H\mathrm{H} atoms.
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Answer from Sia
Posted 10 months ago
Solution
1
Identify the reaction type: The given reaction involves a hydrocarbon with a triple bond (an alkyne) and the reagents Li/NH3\mathrm{Li} / \mathrm{NH}_{3}. This is indicative of a reduction reaction, specifically a Birch reduction
2
Determine the product: In a Birch reduction, the alkyne is partially reduced to a trans-alkene. The triple bond becomes a double bond with one hydrogen added to each of the carbons that were previously triple-bonded, in a trans configuration. Since stereochemistry is not a consideration here, we will simply draw the alkene
3
Draw the organic product: The product of the reaction will be H3CCH2C=CCH2CH3\mathrm{H}_{3}\mathrm{C}-\mathrm{CH}_{2}-\mathrm{C}=\mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{3}, with the double bond between the two central carbon atoms
Answer
H3CCH2C=CCH2CH3\mathrm{H}_{3}\mathrm{C}-\mathrm{CH}_{2}-\mathrm{C}=\mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{3}
Key Concept
Birch reduction of alkynes
Explanation
The Birch reduction converts an alkyne to a trans-alkene by adding hydrogen atoms to each of the carbons that were involved in the triple bond.

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