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青州's Question
Chemistry
Posted 9 months ago

As many as 18 different Diels-Alder products can be obtained by heating a mixture of 1,3-butadiene and 2-methyl-1,3-butadiene. Identify the products. Please name them as well.
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Answer from Sia
Posted 9 months ago
Solution
1
Identify the reactants: The reactants in this Diels-Alder reaction are 1,3-butadiene and 2-methyl-1,3-butadiene. Both of these compounds are dienes, which means they have two double bonds
2
Understand the Diels-Alder reaction: The Diels-Alder reaction is a [4+2] cycloaddition reaction between a diene and a dienophile, resulting in the formation of a six-membered ring. In this case, both reactants are dienes, so they can react with each other in various combinations
3
Possible combinations: Since both reactants are dienes, they can react in different ways to form various products. The possible combinations include: - 1,3-butadiene reacting with another 1,3-butadiene - 1,3-butadiene reacting with 2-methyl-1,3-butadiene - 2-methyl-1,3-butadiene reacting with another 2-methyl-1,3-butadiene
4
Identify the products: The products of these reactions will be different cyclohexene derivatives. Here are some possible products: - Cyclohexene - 4-methylcyclohexene - 3-methylcyclohexene - 1,2-dimethylcyclohexene - 1,3-dimethylcyclohexene - 1,4-dimethylcyclohexene - 1,5-dimethylcyclohexene - 1,6-dimethylcyclohexene - 2,3-dimethylcyclohexene - 2,4-dimethylcyclohexene - 2,5-dimethylcyclohexene - 2,6-dimethylcyclohexene - 3,4-dimethylcyclohexene - 3,5-dimethylcyclohexene - 3,6-dimethylcyclohexene - 4,5-dimethylcyclohexene - 4,6-dimethylcyclohexene
5
Naming the products: The products can be named based on the position and number of methyl groups on the cyclohexene ring. For example: - Cyclohexene - 4-methylcyclohexene - 1,2-dimethylcyclohexene - 1,3-dimethylcyclohexene - 1,4-dimethylcyclohexene
Answer
Cyclohexene, 4-methylcyclohexene, 1,2-dimethylcyclohexene, 1,3-dimethylcyclohexene, 1,4-dimethylcyclohexene
Key Concept
Diels-Alder reaction between dienes
Explanation
The Diels-Alder reaction between 1,3-butadiene and 2-methyl-1,3-butadiene can produce various cyclohexene derivatives depending on the combination of reactants and the positions of the substituents.

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