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Sia

青州's Question
Chemistry
Posted 10 months ago

A 25.0 mL25.0 \mathrm{~mL} sample containing nickel ions (Ni2+)(\mathrm{Ni} 2+) is treated with excess sodium hydroxide (NaOH)(\mathrm{NaOH}) solution, and the resulting precipitate is filtered and ignited to form nickel (II) oxide (NiO). If the mass of the obtained NiO\mathrm{NiO} is 0.325 g0.325 \mathrm{~g}, calculate the concentration of nickel ions in the original sample.
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Answer from Sia
Posted 10 months ago
Solution
1
Write the balanced chemical equation: The reaction between Ni2+\mathrm{Ni}^{2+} ions and NaOH\mathrm{NaOH} leads to the formation of Ni(OH)2\mathrm{Ni(OH)_2}, which upon heating decomposes to form NiO\mathrm{NiO} and H2O\mathrm{H_2O}. The balanced chemical equations are: Ni2++2NaOHNi(OH)2\mathrm{Ni}^{2+} + 2\mathrm{NaOH} \rightarrow \mathrm{Ni(OH)_2} \downarrow and Ni(OH)2NiO+H2O\mathrm{Ni(OH)_2} \rightarrow \mathrm{NiO} + \mathrm{H_2O}
2
Calculate moles of $\mathrm{NiO}$: Use the molar mass of NiO\mathrm{NiO} to find the moles of NiO\mathrm{NiO} produced. The molar mass of NiO\mathrm{NiO} is approximately 58.69 g/mol58.69 \mathrm{~g/mol}. The moles of NiO\mathrm{NiO} are calculated by the formula: moles=massmolar mass\text{moles} = \frac{\text{mass}}{\text{molar mass}}. Thus, moles of NiO=0.325 g58.69 g/mol\text{moles of NiO} = \frac{0.325 \mathrm{~g}}{58.69 \mathrm{~g/mol}}
3
Relate moles of $\mathrm{NiO}$ to moles of $\mathrm{Ni}^{2+}$: From the balanced chemical equation, each mole of NiO\mathrm{NiO} comes from one mole of Ni2+\mathrm{Ni}^{2+}. Therefore, the moles of Ni2+\mathrm{Ni}^{2+} in the original sample are equal to the moles of NiO\mathrm{NiO}
4
Calculate concentration of $\mathrm{Ni}^{2+}$ ions: The concentration of Ni2+\mathrm{Ni}^{2+} ions in the original sample is calculated using the formula: concentration=moles of solutevolume of solution in liters\text{concentration} = \frac{\text{moles of solute}}{\text{volume of solution in liters}}. Convert the volume from mL to L by dividing by 1000. Thus, concentration of Ni2+=moles of Ni2+0.0250 L\text{concentration of Ni}^{2+} = \frac{\text{moles of Ni}^{2+}}{0.0250 \mathrm{~L}}
Answer
[Insert final answer here]
Key Concept
Stoichiometry and molar mass are used to relate the mass of a compound to the amount of substance and to calculate the concentration of a solution.
Explanation
The concentration of nickel ions in the original sample is determined by calculating the moles of NiO\mathrm{NiO} produced and using stoichiometry to relate it back to the moles of Ni2+\mathrm{Ni}^{2+}, followed by calculating the concentration with the volume of the sample.

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