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Chemistry
Posted 10 months ago
6. Calculate the most probable radius at which an electron will be found when it occupies a 1s orbital of a hydrogen atom.
 hint: Ψ1s(x)=1π(1a0)32exa0a is the Bohr radius  radial probabilit p(r)=4πr2Ψ1s(x)2
\text { hint: } \begin{aligned}
& \Psi_{1 s}(x)=\frac{1}{\sqrt{\pi}}\left(\frac{1}{a_{0}}\right)^{\frac{3}{2}} e^{-\frac{x}{a_{0}}} \text {; } a_{\circ} \text { is the Bohr radius } \\
& \text { radial probabilit } p(r)=4 \pi r^{2}\left|\Psi_{1 s}(x)\right|^{2}
\end{aligned}
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Answer from Sia
Posted 10 months ago
Solution
1
Express the radial probability density function: The radial probability density function p(r)p(r) for an electron in a 1s orbital is given by the square of the radial part of the wave function Ψ1s(r)2|\Psi_{1s}(r)|^2 multiplied by the surface area of a sphere 4πr24\pi r^2
2
Substitute the wave function: The given wave function for the 1s orbital is Ψ1s(r)=1π(1a0)32era0\Psi_{1s}(r) = \frac{1}{\sqrt{\pi}}\left(\frac{1}{a_0}\right)^{\frac{3}{2}} e^{-\frac{r}{a_0}}. We need to square this and multiply by 4πr24\pi r^2 to get p(r)p(r)
3
Calculate $p(r)$: The radial probability density function is p(r)=4πr2Ψ1s(r)2=4πr2(1π(1a0)32era0)2p(r) = 4\pi r^2 \left|\Psi_{1s}(r)\right|^2 = 4\pi r^2 \left(\frac{1}{\sqrt{\pi}}\left(\frac{1}{a_0}\right)^{\frac{3}{2}} e^{-\frac{r}{a_0}}\right)^2. Simplifying this gives p(r)=4r2a03e2ra0p(r) = \frac{4r^2}{a_0^3} e^{-\frac{2r}{a_0}}
4
Find the maximum of $p(r)$: To find the most probable radius, we need to find the value of rr that maximizes p(r)p(r). This is done by taking the derivative of p(r)p(r) with respect to rr and setting it equal to zero
5
Differentiate and solve for $r$: Differentiating p(r)p(r) with respect to rr gives dp(r)dr=4a03(2re2ra02r2a0e2ra0)\frac{dp(r)}{dr} = \frac{4}{a_0^3}(2r e^{-\frac{2r}{a_0}} - \frac{2r^2}{a_0}e^{-\frac{2r}{a_0}}). Setting dp(r)dr=0\frac{dp(r)}{dr} = 0 and solving for rr gives r=a0r = a_0
Answer
The most probable radius at which an electron will be found when it occupies a 1s orbital of a hydrogen atom is the Bohr radius a0a_0.
Key Concept
The most probable radius for an electron in a 1s orbital is found by maximizing the radial probability density function.
Explanation
The most probable radius is the value of rr at which the radial probability density function p(r)p(r) reaches its maximum. For a 1s orbital, this occurs at the Bohr radius a0a_0.

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