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青州's Question
Chemistry
Posted 10 months ago

55) What is the concentration of Cu2+\mathrm{Cu}^{2+} in the following cell at 25C25^{\circ} \mathrm{C} if the cell voltage is 0,952 V0,952 \mathrm{~V} ?
ZnZn2+(0.125M)Cu2+(?)CuCu2++2eCu(s)E=0.340 VZn2++2eZn(s)E=0.763 V
\begin{array}{l}
\mathrm{Zn}\left|\mathrm{Zn}^{2+}(0.125 \mathrm{M}) \| \mathrm{Cu}^{2+}(?)\right| \mathrm{Cu} \\
\mathrm{Cu}^{2+}+2 \mathrm{e}^{-} \rightarrow \mathrm{Cu}(\mathrm{s}) E^{\circ}=0.340 \mathrm{~V} \\
\mathrm{Zn}{ }^{2+}+2 \mathrm{e}^{-} \rightarrow \mathrm{Zn}(\mathrm{s}) E^{\circ}=-0.763 \mathrm{~V}
\end{array}

A) 9×104M9 \times 10^{-4} \mathrm{M}
B) 0.6M0.6 \mathrm{M}
C) 1×102M1 \times 10^{-2} \mathrm{M}
D) 1×106M1 \times 10^{-6} \mathrm{M}
E) 4×104M4 \times 10^{-4} \mathrm{M}
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Answer from Sia
Posted 10 months ago
A
Key Concept
Nernst Equation
Explanation
The Nernst equation relates the cell potential to the standard electrode potential, temperature, and activities (or concentrations) of the chemical species involved in the redox reaction. It is used to calculate the unknown concentration of Cu2+\mathrm{Cu}^{2+} given the cell voltage.

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