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Chemistry
Posted 10 months ago

2. Write the appropriate resonance structure of the followings. (2(2 pts)
(a)
(b)
3. Place the necessary arrow(s) to convert the structures in the left to the ones in the right (4pts)(4 \mathrm{pts})
(a)
(b)
Name \qquad
1. Answer the following miscellaneous questions:
I.D.
\qquad
(4(4 pts)
undefined line-segment formula  or stick-like diagram  convert to 
\xrightarrow[\begin{array}{l}
\text { line-segment formula } \\
\text { or stick-like diagram }
\end{array}]{\text { convert to }}

b) Draw the most stable conformational structure for 2-methylpentane looking down at C2-C3
d) Indicate the numbers of mono-chlorinated products for:
e) What are the structures of C6H20\mathrm{C}_{6} \mathrm{H}_{20} if its ozonolysis reaction in the presence of Zn\mathrm{Zn} and HCl\mathrm{HCl} produces CH3C(=O)CH2CH2C(=O)CH3\mathrm{CH}_{3} \mathrm{C}(=\mathrm{O}) \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{C}(=\mathrm{O}) \mathrm{CH}_{3}
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Answer from Sia
Posted 10 months ago
Solution
1
Convert to line-segment formula: To convert a skeletal structure into a line-segment or stick-like diagram, each vertex or end of a line represents a carbon atom, and the lines represent bonds between them. Hydrogen atoms are not shown but are implied to complete each carbon's four bonds
2
Draw the most stable conformation for 2-methylpentane: The most stable conformation of 2-methylpentane looking down the C2-C3 bond is the one that minimizes steric hindrance. This is typically a staggered conformation where the methyl group at C2 is as far away as possible from the other substituents
3
Number of monochlorinated products: To determine the number of possible monochlorinated products for a given alkane, identify the number of unique types of hydrogen atoms. Each unique type, when replaced by chlorine, will give a different monochlorinated product
4
Ozonolysis products: The ozonolysis of an alkene leads to the cleavage of the double bond and the formation of two carbonyl compounds. The given product suggests the original alkene had a double bond between the second and third carbon atoms in a six-carbon chain
1 Answer
The line-segment or stick-like diagram will show all the carbon atoms and the bonds between them, with implied hydrogens to satisfy the tetravalency of carbon.
2 Answer
The most stable conformation of 2-methylpentane is a staggered conformation with the methyl group at C2 anti to the largest group on C3.
3 Answer
The number of possible monochlorinated products depends on the number of unique types of hydrogen atoms in the alkane.
4 Answer
The structures resulting from the ozonolysis of C6H10C_6H_{10} in the presence of Zn and HCl are two molecules of propanone, CH3C(=O)CH3CH_3C(=O)CH_3.
Key Concept
Line-segment diagrams represent organic molecules with lines for bonds and vertices for carbon atoms, with hydrogen atoms being implicit.
Explanation
This representation simplifies the visualization of organic structures and is commonly used in organic chemistry.
Key Concept
The most stable conformation of an alkane minimizes steric hindrance between substituents.
Explanation
In 2-methylpentane, the staggered conformation with the methyl group anti to the largest substituent on the adjacent carbon is the most stable due to reduced steric clashes.
Key Concept
Unique types of hydrogen atoms in an alkane determine the number of monochlorinated products.
Explanation
Each type of hydrogen can be replaced by chlorine to give a distinct monochlorinated alkane, so identifying these types is key to determining the number of products.
Key Concept
Ozonolysis cleaves double bonds to form carbonyl compounds.
Explanation
The reaction splits the alkene into two parts, each becoming a carbonyl compound, which helps deduce the structure of the original alkene.

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